The simple answer is yes, but printing a barcode is not a simple matter. If you want to print barcodes, and you don't know anything about them, you'll have to educate yourself on them. My go-to website for learning about barcodes is https://www.barcodefaq.com
There are several good links on this page. I'll just give you a couple I think are very useful. The next link describes different barcode types:
https://www.barcodefaq.com/barcoding-for-beginners/#Choosing_bar_code_type
If you know that you want to print UPC barcode labels on the ML-5000, you can skip right to the next link which gives a lot of information on the UPC barcodes:
https://www.barcodefaq.com/1d/upc-ean/
It's a lot of reading but well worth the time if you need to print barcodes.
The barcode image in this blog post is actually the UPC-A barcode for the ML-5000 label that was created on
https://www.free-barcode-generator.net/upc-a/